Allotropes are all the rage? Or at least sending Conan O'Brien over a very funny edge! The bit was inspired by
this article in the NY Times science section. I'm not nearly this riveting when I lecture about allotropes, I've got to admit.
O'Brien gets the chemistry nearly right. My only quibble would be that he calls the different forms (the diagrams are the real thing, by the way) different phases, which they aren't really. They are technically allotropes, different structural forms within the same phase or state of matter. The quintessential example is the allotropes of solid carbon, graphite and diamond and a
few others. All that said, when you draw a phase diagram for an element, you show the allotropes on it, and many chemists would characterize the change from one allotrope to another as a phase change.
Oxygen has some fascinating solid allotropes, including one that is a
blue solid at room temperature!
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